Superwettable and chemically stable waste silk fabric and degummed silk were used in this study for treatment of oily wastewater and oil/solvent recovery. Silk functionalized with a nano-fluoro dispersion showed a superhydrophobic and oleophilic nature. The functionalized silk demonstrated superoleophilicity towards petroleum oils and organic solvents, and exhibited filtration efficiencies of more than 95%, and up to 70% till 25 re-usable cycles. Furthermore, the functionalized silk materials demonstrated high permeation flux of 584 L.m-2.h-1 (for Diesel) for continuous oil-water separation operation. The pH based study in highly acidic and alkaline mediums (pH from 1 to 13) showed excellent stability of nano-fluoro coated silk. Thermogravimetric analysis showed thermal stability up to 250 °C, and 400 °C, for functionalized waste silk, and degummed silk, respectively. FE-SEM analysis revealed randomly oriented spindle shaped nano particles anchored on the silk surface exhibiting hierarchical patterns, as required for the superhydrophobic Cassie-Baxter state. The rate absorption study showed close curve fitting for pseudo second order kinetics (R2 = 0.999), which indicated physical absorption process. BET analysis confirmed the porous nature, while the elemental XPS and EDX analysis confirmed strong bonding and uniform coating of fluoro nanoparticles on silk surface. The results demonstrated that nano-fluoro dispersion functionalized silk can be successfully employed for effective oil/solvent-water filtration, oil/solvent-spill cleanups, and treatment of oily wastewater for protection of water resources.
Keywords: Degummed silk; Nano-fluoro dispersion; Oil & solvent recovery; Surface functionalization; Waste silk fabric.
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