In situ chemical oxidation (ISCO) is a popular remediation technique for hydrocarbon-contaminated soil and groundwater. A range of oxidising agents and activators are available for ISCO; however, selection is usually based on contaminant destruction which is time-consuming and impacted by sample heterogeneity based on 1-10 g sample contaminant analysis. In this paper, we demonstrate the use of an automated respirometer, measuring CO2 production, as a rapid and reliable approach for activator type and concentration selection. The approach is demonstrated based on tests in matrices of different types (loam soil and sand). In both matrices, CO2 production was significantly increased following sodium persulphate (SPS) oxidation with iron activation in a concentration-dependant manner. Alkaline activation led to no increased CO2 production compared to SPS addition without activation. The approach will provide greater confidence in treatability testing and reagent efficiency in ISCO projects.
Keywords: Chemical oxidation; Groundwater; Persulphate; Remediation; Respirometry; Soil.
© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.