Contrary to classical thermodynamics, which deals with systems in thermal equilibrium, partially ionized gases generally do not reach thermal equilibrium. Nonextensive statistical mechanics has helped extend classical thermodynamics to nonequilibrium ionized gas. However, the fundamental question on whether the statistics of non-Maxwellian electrons satisfy the laws of thermodynamics has not been resolved. Here, we verify the thermodynamic laws of reversible and adiabatic processes for a magnetically expanding ionized gas. Together with the experimental evidence of the non-Maxwellian electron distribution, the κ distribution, which measures the thermal equilibrium states, shows the Tsallis entropy to be nearly constant and the polytropic index to be close to adiabatic values along a divergent magnetic field. These results verify that the collisionless magnetic expansion of a nonequilibrium plasma is reversible and adiabatic, and an isentropic process is the origin of the high-energy tail of the energy distribution far downstream.