Bimetallic Cd/Zr-UiO-66 material as a turn-on/off probe for As5+/Fe3+ in organic media

Abstract

In this work, a series of bimetallic Cd/Zr-UiO-66 materials were successfully synthesized for fluorescence sensing toward traces of As⁵⁺ and Fe³⁺ via a one-pot method. Interestingly, the obtained bimetallic Cd/Zr-UiO-66 (1:9) can be served as turn-on probe for As⁵⁺ as well as turn-off probe for Fe³⁺. The LODs of Cd/Zr-UiO-66 (1:9) toward As⁵⁺ and Fe³⁺ were calculated to be 5.4 μM and 4.3 μM, respectively, indicating its effective sensing properties for As⁵⁺ and Fe³⁺ in methanol media. Moreover, even in the presence of other potentially interfering toxic metal ions such as As³⁺, Cd²⁺ and Pb²⁺, Cd/Zr-UiO-66 (1:9) still presented good anti-interference abilities. Additionally, the removal efficiency of Cd/Zr-UiO-66 (1:9) toward As⁵⁺ was higher than 70% when the initial As⁵⁺ was lower than 50 mg/L. The fluorescence quenching of Fe³⁺ were mainly due to the competitive absorption of excitation source and RET, while the ACE mechanism was mostly responsible for the enhancement of As⁵⁺. More importantly, this job might pave the way for future researches and applications on sensing As⁵⁺ and Fe³⁺.

Keywords: Arsenic; Bimetal-organic framework; Fluorescence; Iron; Removal; Sensing.