A bifunctional nanozyme of carbon dots-mediated Co9S8 formation

Abstract

Controlling the size of nanocrystals and inhibiting their agglomeration are of paramount importance for achieving ideal catalytic performance. Here we discovered that carbon dots (CDs) are not only able to serve as reductants but also as stabilizers of ultrasmall Co₉S₈ nanocrystals by means of their surface terminal groups. As a result, ultrasmall Co₉S₈ nanocrystals are incorporated into porous carbon nanosheets formed by splicing CDs. The resultant nanocomposites display a rich pore structure accompanying with large specific surface area and outstanding bifunctional performances to mimic the catalytic activity of peroxidase and oxidase without exerting any external energy. More importantly, the unique architecture endows Co₉S₈ nanocrystals with high stability and good durability. The nanocomposites have been demonstrated as a colorimetric sensor for detection of ascorbic acid with a superior anti-interference ability as well as a detection limit of 0.2 μM. Our findings open new synthetic opportunities by tuning the interaction of CDs with the surrounding environment and enable advanced applications such as biomedicine and catalytic transformations.

Keywords: Carbon dots; Co(9)S(8) nanoparticle; Controllable reduction; Nanocomposite.