A facile route to novel stretchable conductive elastomers with micro-ionicgel acting as conductive fillers was developed via oil-in-oil Pickering emulsion polymerization of nonpolar monomers A and a mixture of polar monomers B and ionic liquids (ILs). Oil-in-oil Pickering emulsions were first fabricated by mixing n-butyl acrylate (n-BA), acrylic acid (AA), ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate, [EMIM]+[BF4]-), and alkyl vinyl-functionalized silica particles. The emulsion structure was directly observed using the dye-labeled AA-IL phase by confocal fluorescence microscopy. Upon polymerization, the IL-based conductive composite elastomers were obtained, where the continuous phase and the dispersed phase are poly(n-butyl acrylate) (PnBA) and poly(acrylic acid) containing ILs (PAA-ILs, referred to as micro-ionicgel), respectively. The PnBA matrix endows the formed elastomer with extremely large stretchability (up to 12 000% strain) and insensitivity to moisture. The micro-ionicgels PAA-ILs not only contribute to good conductivity but can also prevent the leakage of ILs upon stretching or folding. The electrical impedance-based stretchable sensors fabricated using this IL elastomer could detect various human motions including the bending of a finger, wrist, elbow, and knee. Therefore, the as-developed sensors show promising applications for human-machine interfaces of flexible wearable sensors.
Keywords: Pickering emulsion; conductive elastomer; ionic liquids; ultrastretchable; wearable sensor.