All-solid-state Z-scheme Ag3PO4/CSs/AgBr heterostructures for efficient visible-light photocatalysis and the photocatalytic mechanism

Nan Li; Guodong Fan; Miaomiao Fan; Fan Wu; Guoxian Zhang; Di Fan

doi:10.1039/d1dt02937a

All-solid-state Z-scheme Ag₃PO₄/CSs/AgBr heterostructures for efficient visible-light photocatalysis and the photocatalytic mechanism

Dalton Trans. 2021 Nov 9;50(43):15602-15611. doi: 10.1039/d1dt02937a.

Authors

Nan Li^{1

2}, Guodong Fan^{1

2}, Miaomiao Fan³, Fan Wu^{1

2}, Guoxian Zhang^{1

2}, Di Fan^{4

5}

Affiliations

¹ Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science & Technology, Xi'an 710021, China. fangd@sust.edu.cn.
² College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021, Shaanxi, China.
³ Shaanxi Shen-Wei Coal Pipeline Transportation Limited Liability Company, Xi'an 710065, China.
⁴ Department of Information Engineering, Shaanxi Polytechnic Institute, Xianyang 712000, Shaanxi, China.
⁵ Department of Electronic and Electrical Engineering, University of Sheffield, Sheffield S10 2TN, UK.

PMID: 34668504
DOI: 10.1039/d1dt02937a

Abstract

A novel solid-state Z-scheme photocatalyst Ag₃PO₄/CSs/AgBr (carbon spheres, CSs) was rationally designed and successfully synthesized via a facile hydrothermal coprecipitation reaction. AgBr and Ag₃PO₄ were effectively loaded on the surface of the CSs and Ag₃PO₄/CSs/AgBr showed wide visible light absorption and superior photocatalytic performance. On the basis of ultraviolet photoelectron spectroscopy (UPS) analysis and scavenger reactions, a possible photocatalytic reaction mechanism for Ag₃PO₄/CSs/AgBr is proposed. The CSs act as a charge carrier transfer bridge for constructing the all-solid-state Z-scheme photocatalyst. The photogenerated electrons from Ag₃PO₄ and holes from AgBr congregate and recombine in the CSs phase, leaving photogenerated electrons with strong reduction abilities in the conduction band (CB) of AgBr and holes with strong oxidation abilities in the valence band (VB) of Ag₃PO₄. Some Ag⁺ ions accept electrons and turn to Ag nanoparticles (NPs), leading to the surface plasmon resonance of Ag NPs on AgBr. Therefore, the photocatalytic performance and stability were significantly improved.