Solidification/stabilization of landfill leachate concentrate contaminants using solid alkali-activated geopolymers with a high liquid solid ratio and fixing rate

Hao Zhang; Zehua Ji; Yuxin Zeng; Yuansheng Pei

doi:10.1016/j.chemosphere.2021.132495

Solidification/stabilization of landfill leachate concentrate contaminants using solid alkali-activated geopolymers with a high liquid solid ratio and fixing rate

Chemosphere. 2022 Feb;288(Pt 2):132495. doi: 10.1016/j.chemosphere.2021.132495. Epub 2021 Oct 13.

Authors

Hao Zhang¹, Zehua Ji¹, Yuxin Zeng¹, Yuansheng Pei²

Affiliations

¹ State Key Laboratory of Water Environment Simulation, Ministry of Education, School of Environment, Beijing Normal University, Beijing, 100875, China; The Key Laboratory of Water and Sediment Sciences, Ministry of Education, School of Environment, Beijing Normal University, Beijing, 100875, China.
² State Key Laboratory of Water Environment Simulation, Ministry of Education, School of Environment, Beijing Normal University, Beijing, 100875, China; The Key Laboratory of Water and Sediment Sciences, Ministry of Education, School of Environment, Beijing Normal University, Beijing, 100875, China. Electronic address: yspei@bnu.edu.cn.

PMID: 34655647
DOI: 10.1016/j.chemosphere.2021.132495

Abstract

Landfill leachate concentrate (LLC) is a highly toxic wastewater that contains many refractory contaminants. One of the technical and economic treatment methods is solidification/stabilization (S/S), where the contaminants of LLC can be sealed in one step to achieve zero wastewater discharge. This study presents the S/S of LLC contaminants using solid alkali-activated geopolymers prepared from blast furnace slag (BFS) and powdery sodium silicate. The stability of the formed geopolymer was studied through unconfined compressive strength (UCS) and leaching tests. The strongest UCS was obtained when the modulus of the activator was 1.16 with a high liquid/solid ratio of 0.64. BFS-based geopolymers presented excellent LLC S/S efficiency. The S/S rates of TOC, COD_Cr, NH₃-N, Cl^-, and SO₄^2- were 81%, 89%, 97%, 97%, and 78%, respectively. The S/S rates of heavy metals, i.e., Cd and Pb, were all more than 99%. The results of microstructure characterization showed that the S/S mechanism of LLC pollutants was the dual effect of physical closure and chemical stability. Cl^- and SO₄^2- were respectively stabilized in the crystal lattice by Friedel's salt and calcium sulfate, respectively, while organic matter and NH₃-N were physically encapsulated in the dense structure of the geopolymer. Overall, BFS based geopolymers demonstrated high treatment capacity and excellent S/S efficiency, and have a potential application prospects in LLC treatment.

Keywords: Blast furnace slag; Geopolymer; Landfill leachate concentrate; Solidification; Stabilization.

MeSH terms

Alkalies*
Water Pollutants, Chemical*

Substances

Alkalies
Water Pollutants, Chemical