Removing ammonium from contaminated water using Purolite C100E: batch, column, and household filter studies

Abstract

Ammonium removal from drinking water to protect human and environmental health is one of the major global concerns. This study evaluates the performance of Purolite C100E, a commercial cation exchange resin, in eliminating ammonium in synthetic and real contaminated groundwater. The results demonstrate that the pH operation range of the resin for better ammonium removal is 3 to 8. Lower ammonium removal at low and high pH occurred due to competition from H⁺ and loss of ammonium as ammonia gas, respectively. Equilibrium data of ammonium removal fitted both the Langmuir and Freundlich isotherm models with the maximum Langmuir ion exchange capacities for initial ammonium concentrations of 10-200 mg/L and 50-2000 mg/L, reaching 18.37 mg/g and 40.16 mg/g, respectively. The presence of co-ions in the water reduced the ammonium removal efficiencies slightly (< 12%) in the order Mg²⁺ > Ca²⁺ > K⁺. The higher affinity of ammonium to adsorbent is due to its lower hydrated ionic radius and H-bonding. The maximum exchange capacity in the fluidized bed studies of the original Purolite C100E (bed height 27 cm, resin weight 75 g, initial ammonium concentration 17.4 mg/L, filtration velocity 0.5 m/h) was 10.48 mg/g. It progressively reduced slightly after three regeneration cycles to 8.79 mg/g. The column breakthrough data satisfactorily fitted the Thomas model. A household filter cartridge packed with 4 kg Purolite C100E (80 cm height) and operated at a filtration velocity of 1.9 m/h in Vietnam successfully reduced the initial 6 mg NH₄⁺/L in groundwater (after sand filter pre-treatment) to well below the Vietnam drinking water standard (3 mg/L-QCVN 01:2009/BYT) continuously for 1 week, suggesting that such a filter can be adopted in rural areas to successfully remove ammonium from groundwater.

Keywords: Ammonium removal; Contaminated water; Household water filter; Ion exchange; Purolite C100E resin.