Low-cost, stable, and highly active electrocatalysts for oxygen reduction reaction (ORR), especially for pH-universal ORR, are vital for developing numerous renewable energy devices. Herein, a hierarchical N, S-codoped porous carbon-based catalyst (ZFP-800) coupled with abundant FeS/ZnS heterojunctions was facilely prepared via direct pyrolysis of a Ferrocene-crosslinked pyrrole hydrogel composited with zeolitic imidazolate framework-8 (ZIF-8) templates. Compared with the heterojunction-free catalytic activity, the ZFP-800 catalytic activity was significantly higher in pH-universal ranges. Moreover, the ZFP-800 exhibited competitive ORR performance to commercial Pt/C (20%) in various electrolytes, in terms of onset (Eonset), half-wave potentials (E1/2), limiting current density (JL), durability, and methanol immunity. For instance, it exhibited super ORR catalytic activity on Eonset and E1/2, and exceeded that of the benchmark Pt/C in both the alkaline and neutral media. Furthermore, the application of ZFP-800 as a cathode catalyst in a home-made Zn-air battery demonstrated its operation capability in ambient conditions with a competitive performance on the specific energy density (828 mA·h·gZn-1), maximum discharge power density (205.6 mW·cm-2), rate performance, and the long-term stability (188 h at 5 mA·cm-2). This study can facilitate the development of advanced heterojunction-based materials for renewable energy applications.
Keywords: FeS/ZnS heterojunction; Polypyrrole hydrogel; Whole pH ORR; ZIF-8-template; Zn-air battery.
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