Enhanced performance of photocatalytic treatment of Congo red wastewater by CNTs-Ag-modified TiO2 under visible light

Abstract

In order to improve the treatment efficiency of printing and dyeing wastewater, the carbon nanotubes-silver-modified-titanium dioxide (CNTs-Ag-TiO₂, CAT) ternary composite was prepared by a mechanical mixing method. It was found that the morphology of the prepared CAT sample was uniformly coated with strips of CNTs, speckled Ag, and lumpy TiO₂. The (002) crystal plane of CNTs, the (101) crystal plane of TiO₂, and the (111) crystal plane of Ag were observed, which possessed functional groups such as Ti-OH and Ti-O-C, indicating that the prepared CAT sample had photocatalytic reaction sites. The visible light utilization of titanium dioxide can be improved. The treatment effect of different proportions of CNTs-Ag-TiO₂ on Congo red wastewater was tested, and the results showed that the optimum degradation effect of Congo red wastewater was CNTs: Ag = 10:1, and the doped amount of CNTs/Ag was 15%, and the removal rate of Congo red wastewater could reach 100% within 140 min. The excellent removal effect of CAT ternary composite on Congo red wastewater provided a new idea and way for the modification of TiO₂ and its composites for the potential of organic dyes degradation.

Keywords: CNTs-Ag-TiO2 ternary composite; Congo red wastewater; Degradation efficiency; Photocatalysis; Visible light.