Gas samples were collected from 25 m long horizontal boreholes drilled into the excavation field at 10° inclination to the longwall face in two mining areas, Pesje and Preloge, in the Velenje Coal Mine, Slovenia, from 2013 to 2018. The degassing mechanism of coalbed gas and its stable isotopic composition (δ13CCO2, δ13CCH4, and δ2HCH4) were investigated in boreholes in advance of eight working faces. The major coalbed gas constituents were CO2 and methane. Gas concentrations and isotope values revealed that the methane is biogenic in origin with δ13CCH4 values of -69.4 to -29.5 ‰, δ2HCH4 values of -301 to -222 ‰, and a fractionation factor (αCO2-CH4) of 0.998-1.073, suggesting that methane derives from microbial acetate fermentation and CO2 reduction. The carbon dioxide methane index values ranged from 50.0-98.3 vol.% and δ13CCO2 values from -11.8 to -0.5 ‰, indicating that CO2 is biogenic and endogenic in origin. The degassing mechanism results in isotope fractionation of methane and CO2 for carbon isotopes up to 39.9 ‰ and up to 8.5 ‰, respectively, depending on the position of the excavation fields in space, e.g. under pre-mined coal area, fresh overburden.
Keywords: Carbon-13; Slovenia; Velenje Basin; carbon dioxide; coalbed gas; excavation fields; gas composition; isotope geochemistry; methane; spatial distribution.