New chitosan Schiff base and its nanocomposite: Removal of methyl green from aqueous solution and its antibacterial activities

Int J Biol Macromol. 2021 Dec 1:192:1-6. doi: 10.1016/j.ijbiomac.2021.09.192. Epub 2021 Oct 4.

Abstract

New chitosan Schiff base (CS-NB) and its CS-NB-NiFe nanocomposite have been prepared and characterized by FTIR spectroscopy, XRD, SEM and DSC. FT-IR spectra and XRD patterns revealed the preparation of chitosan Schiff base CS-NB and its CS-NB-NiFe nanocomposite. DSC demonstrated the endo and exothermic correspondence the evaporation of solvent and decomposition of pyranose ring, respectively. Antibacterial activities was evaluated for the as-prepared compounds against two Gram-positive (Staphylococcus aureus and Bacillus cereus) and two Gram-negative (Escherichia coli and Pseudomonas aeruginosa) bacteria and the results shows that the antibacterial activities of the compounds are found to be stronger than that of chitosan. The order of antibacterial effect according to inhibitory zone around is as follows: S. aureus > E. coli > B. cereus > P. aeruginosa. In addition, the removal of methyl green (MG) dye using CS-NB and its CS-NB-NiFe nanocomposite were analyzed and results showed that the compounds can be effectively used to remove of MG from aqueous solution. Results show that the percentage removal of MG by nanocomposite is higher than Schiff base.

Keywords: Adsorption; Antibacterial activities; Chitosan Schiff base; Methyl green; Nanocomposite; Nanoparticles.

MeSH terms

  • Adsorption
  • Anti-Bacterial Agents / chemistry*
  • Anti-Bacterial Agents / pharmacology*
  • Chemical Phenomena
  • Chitosan / chemistry*
  • Kinetics
  • Methyl Green / chemistry*
  • Microbial Sensitivity Tests
  • Molecular Structure
  • Nanocomposites / chemistry*
  • Nanocomposites / ultrastructure
  • Nanoparticles
  • Schiff Bases / chemistry*
  • Spectroscopy, Fourier Transform Infrared
  • X-Ray Diffraction

Substances

  • Anti-Bacterial Agents
  • Schiff Bases
  • Methyl Green
  • Chitosan