The successful integration of well-designed micro-nanomotors (MNMs) with diverse functional systems, such as, living systems, remote actuation systems, intelligent sensors, and sensing systems, offers many opportunities to not only endow them with diverse functionalization interfaces but also bring augmented or new properties in a wide variety of applications. Core-shell structured MNM systems have been considered to play an important role in a wide range of applications as they provide a platform to integrate multiple complementary components via decoration, encapsulation, or functionalization into a single functional system, being able to protect the active species from harsh environments, and bring improved propulsion performance, stability, non-toxicity, multi-functionality, and dispersibility, etc., which are not easily available from the isolated components. More importantly, the hetero-interfaces between individual components within a core-shell structure might give rise to boosted or new physiochemical properties. This review will bring together these key aspects of the core-shell structured MNMs, ranging from advanced protocols, enhanced/novel functionalities arising from diverse functional shells, to integrated core-shell structured MNMs for diverse applications. Finally, current challenges and future perspectives for the development of core-shell structured MNMs are discussed in term of synthesis, functions, propulsions, and applications.
Keywords: core-shell structures; enhanced applications; micro/nanomotors; multifunctionality; shell functionalization; synergistic effects.
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