To follow the effect of the microwave heating path on the structure of coal, eight 50 mm diameter, 30 mm long dry coal cores from the same coal seam with similar pore structure characteristics were microwave-treated using 4 pathways. The T 2 spectrum, pore-volume, temperature, mass, and visual changes of coal samples were analyzed before and after microwave heating. The microwave heating path affected the macropores and microcracks and the crack development mode. When the same microwave energy was applied, microwave heating on the coal was mainly manifested by the opening of closed pores, before the pyrolysis temperature of the coal was reached. Increasing the energy density caused the water vapor to move from constant pressure expansion to constant volume expansion. This resulted in an exponential growth of the mesopore and macropore volumes. Meanwhile, the micropore volume increased due to the collapse of pore structures. As a result, high-power microwave heating could accelerate the vaporization rate of water. The rapid expansion of water vapor volume brought about a microwave heating effect similar to the "steam explosion". The resulting local tensile stress enabled the cracks to develop, expand, and connect to others continuously. Thus, it formed a complex crack network leading to the outside of the coal sample.
© 2021 The Authors. Published by American Chemical Society.