The Role of Surface Curvature in Electrocatalysts

Chemistry. 2022 Jan 3;28(1):e202102915. doi: 10.1002/chem.202102915. Epub 2021 Oct 25.

Abstract

Excessive consumption of fossil fuels has caused unavoidable environmental problems. The development of renewable and clean alternatives is essential for the sustainable and green development of human society. Electrocatalysts are most important parts in these energy-related devices. Recently, scientists found that the surface curvature of electrocatalysts could play an important role for the improvement of catalytic performance and the optimization of intrinsic catalytic activity during electrocatalytic process. The role of surface curvature in electrocatalysts is still under investigating. In this minireview, we summarized the latest progress of electrocatalysts with different surface curvatures and their applications in energy-related applications. This review mainly involves the strategies for preparation of electrocatalysts with different surface curvatures, three typical electrocatalysts with different surface curvatures (curled surface, onion-like structure, and spiral structure), and the potential mechanisms that surface curvature in electrocatalysts affects activities.

Keywords: carbon onions; curled structures; electrocatalysts; spiral structures; surface curvatures.

Publication types

  • Review

MeSH terms

  • Catalysis*
  • Humans