Proton exchange membrane fuel cells (PEMFCs) are promising devices for clean power generation in fuel cell electric vehicles applications. The further request of high-efficiency and cost competitive technology make high-temperature proton exchange membranes utilizing phosphoric acid-doped polybenzimidazole be favored because they can work well up to 180 °C without extra humidifier. However, they face quick loss of phosphoric acid below 120 °C and resulting in the limits of commercialization. Herein UiO-66 derived carbon (porous carbon-ZrO2 ), comprising branched poly(4,4'-diphenylether-5,5'-bibenzimidazole) and polyacrylamide hydrogels self-assembly (BHC1-4) membranes for wide-temperature-range operation (80-160 °C) is presented. These two-phase membranes contained the hygroscopicity of polyacrylamide hydrogels improve the low-temperature proton conductivity, relatively enable the membrane to function at 80 °C. An excellent cell performance of BHC2 membrane with high peak power density of 265 and 656 mW cm-2 at both 80 and 160 °C can be achieved. Furthermore, this membrane exhibits high stability of frequency cold start-ups (from room temperature to 80 °C) and long-term cell test at 160 °C. The improvement of cell performance and stability of BHC2 membrane indicate a progress of breaking operated temperature limit in existing PEMFCs systems.
Keywords: PAM hydrogels; UiO-66-derived carbon; Zr(HPO 4) 2H 2O; ZrO 2; branched OPBI; wide-temperature-range PEM.
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