Influence of Silica Modulus and Curing Temperature on the Strength of Alkali-Activated Volcanic Ash and Limestone Powder Mortar

Abstract

This present study evaluates the effect of silica modulus (M_s) and curing temperature on strengths and the microstructures of binary blended alkali-activated volcanic ash and limestone powder mortar. Mortar samples were prepared using mass ratio of combined Na₂SiO_3(aq)/10 M NaOH_(aq) of 0.5 to 1.5 at an interval of 0.25, corresponding to M_s of 0.52, 0.72, 0.89, 1.05 and 1.18, respectively, and sole 10 M NaOH_(aq). Samples were then subjected to ambient room temperature, and the oven-cured temperature was maintained from 45 to 90 °C at an interval of 15 °C for 24 h. The maximum achievable 28-day strength was 27 MPa at M_s value of 0.89 cured at 75 °C. Samples synthesised with the sole 10 M NaOH_(aq) activator resulted in a binder with a low 28-day compressive strength (15 MPa) compared to combined usage of Na₂SiO_3(aq)/10 M NaOH_(aq) activators. Results further revealed that curing at low temperatures (25 °C to 45 °C) does not favour strength development, whereas higher curing temperature positively enhanced strength development. More than 70% of the 28-day compressive strength could be achieved within 12 h of curing with the usage of combined Na₂SiO_3(aq)/10 M NaOH_(aq). XRD, FTIR and SEM + EDX characterisations revealed that activation with combined Na₂SiO_3(aq)/10 M NaOH_(aq) leads to the formation of anorthite (CaAl₂Si₂O₈), gehlenite (CaO.Al₂O₃.SiO₂) and albite (NaAlSi₃O₈) that improve the amorphosity, homogeneity and microstructural density of the binder compared to that of samples synthesised with sole 10 M NaOH_(aq).

Keywords: alkali-activated mortar; aluminosilicate; curing temperature; limestone powder; microstructure; silica modulus; volcanic ash.