Experimental Measurement and Equilibrium Modeling of Adsorption of Asphaltenes from Various Origins onto the Magnetite Surface under Static and Dynamic Conditions

Mohammad-Reza Mohammadi; Sajjad Ansari; Hamid Bahmaninia; Mehdi Ostadhassan; Saeid Norouzi-Apourvari; Abdolhossein Hemmati-Sarapardeh; Mahin Schaffie; Mohammad Ranjbar

doi:10.1021/acsomega.1c04224

Experimental Measurement and Equilibrium Modeling of Adsorption of Asphaltenes from Various Origins onto the Magnetite Surface under Static and Dynamic Conditions

ACS Omega. 2021 Sep 10;6(37):24256-24268. doi: 10.1021/acsomega.1c04224. eCollection 2021 Sep 21.

Authors

Mohammad-Reza Mohammadi¹, Sajjad Ansari¹, Hamid Bahmaninia¹, Mehdi Ostadhassan², Saeid Norouzi-Apourvari¹, Abdolhossein Hemmati-Sarapardeh^{1

3}, Mahin Schaffie¹, Mohammad Ranjbar^{1

4}

Affiliations

¹ Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman 76188-68366, Iran.
² State Key Laboratory of Continental Shale Hydrocarbon Accumulation and Efficient Development, Ministry of Education, Northeast Petroleum University, Daqing 163318, China.
³ College of Construction Engineering, Jilin University, Changchun 130026, China.
⁴ Department of Mining Engineering, Shahid Bahonar University of Kerman, Kerman 7618868366, Iran.

Abstract

Wettability alterations, permeability reduction of reservoir rocks, and oil production decline may occur as a consequence of asphaltene adsorption and deposition on the surfaces of oil reservoir rocks. Magnetite and other iron minerals are abundant in the rock composition of sandstone reservoirs and cause problems by precipitation and adsorption of polar components of crude oil. The main purpose of this study was to investigate the adsorption of six asphaltene samples of various origins onto the magnetite surface. Characterization of magnetite was performed by Brunauer-Emmett-Teller (BET), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF). Also, FTIR, dynamic light scattering (DLS), and elemental analysis were performed to characterize asphaltenes. Static and dynamic adsorption experiments were carried out to investigate the effects of the water phase, adsorbent size, flow rate, and asphaltene compositions on asphaltene uptake by the magnetite. The results showed that an increase in the nitrogen content and aromatic nature of asphaltenes increased their adsorption on magnetite. The addition of water to the adsorption tests significantly reduced the adsorption amount of asphaltenes on the magnetite. A considerable decrease in asphaltene adsorption was observed with an increase in the flow rate in dynamic tests. This shows that higher flow rates reduce the interaction between adsorbed asphaltenes and asphaltene aggregates in the solution, which reduces the uptake of more asphaltenes. Moreover, adsorbed asphaltene components with a weaker bond are detached from the magnetite surface, which can be attributed to the physisorption of asphaltenes. Eventually, four well-known adsorption isotherm models, namely, Langmuir, Dubinin-Radushkevich, Temkin, and Freundlich were utilized to find the mechanisms of asphaltene adsorption onto the magnetite surface. The Freundlich model seems to provide better estimates for the adsorption of asphaltenes on the magnetite surface. The findings of this study render insights into the better management of oil production in formations with iron-containing rocks.