A strongly Lewis-acidic and fluorescent borenium cation supported by a tridentate formazanate ligand

Chem Commun (Camb). 2021 Sep 21;57(75):9530-9533. doi: 10.1039/d1cc03873g.

Abstract

Lewis acids are highly sought after for their applications in sensing, small-molecule activation, and catalysis. When combined with π-conjugated molecular frameworks, Lewis acids with unique optoelectronic properties can be realized. Here, we use a tridentate formazanate ligand to create a planar, redox-active, fluorescent, and strongly Lewis-acidic borenium cation. We also demonstrate that this compound can act as a colourimetric probe for reactivity.