The potentials at which water dissociation occurs in bipolar membranes (BPM) and the relationship between water dissociation and current-voltage curve characteristics are explored using a novel spectroelectrochemical approach in which an anion exchange membrane is doped with a pH indicator. Using this method, we visually detect a pH change in the BPM resulting from OH- formed during the water dissociation reaction. The color change is measured with a UV/vis spectrometer, while electrochemical characterization of the BPM is performed simultaneously. Additional measurements were performed on BPMs with varying anion and cation exchange membrane layer thickness. Our measurements provide direct evidence of water dissociation occurring within a BPM at cross-membrane potentials below 0.5 V, within the first limiting current density region. We also show that the effects of changing bulk anion and cation exchange layer thickness is highly dependent on the permselectivity of these layers.
Keywords: HMT-PMBI; SPPB; bipolar membranes; electrochemical impedance spectroscopy; hydrocarbon ion-exchange membranes; pH-indicating membrane; permselectivity; spectroelectrochemistry; water dissociation.