Demonstration of valley anisotropy utilized to enhance the thermoelectric power factor

Airan Li; Chaoliang Hu; Bin He; Mengyu Yao; Chenguang Fu; Yuechu Wang; Xinbing Zhao; Claudia Felser; Tiejun Zhu

doi:10.1038/s41467-021-25722-0

Demonstration of valley anisotropy utilized to enhance the thermoelectric power factor

Nat Commun. 2021 Sep 17;12(1):5408. doi: 10.1038/s41467-021-25722-0.

Authors

Airan Li^#¹, Chaoliang Hu^#¹, Bin He², Mengyu Yao², Chenguang Fu³, Yuechu Wang¹, Xinbing Zhao¹, Claudia Felser², Tiejun Zhu⁴

Affiliations

¹ State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, China.
² Max Planck Institute for Chemical Physics of Solids, Dresden, Germany.
³ State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, China. chenguang_fu@zju.edu.cn.
⁴ State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, China. zhutj@zju.edu.cn.

^# Contributed equally.

Abstract

Valley anisotropy is a favorable electronic structure feature that could be utilized for good thermoelectric performance. Here, taking advantage of the single anisotropic Fermi pocket in p-type Mg₃Sb₂, a feasible strategy utilizing the valley anisotropy to enhance the thermoelectric power factor is demonstrated by synergistic studies on both single crystals and textured polycrystalline samples. Compared to the heavy-band direction, a higher carrier mobility by a factor of 3 is observed along the light-band direction, while the Seebeck coefficient remains similar. Together with lower lattice thermal conductivity, an increased room-temperature zT by a factor of 3.6 is found. Moreover, the first-principles calculations of 66 isostructural Zintl phase compounds are conducted and 9 of them are screened out displaying a p_z-orbital-dominated valence band, similar to Mg₃Sb₂. In this work, we experimentally demonstrate that valley anisotropy is an effective strategy for the enhancement of thermoelectric performance in materials with anisotropic Fermi pockets.