This review is a comprehensive account of reactions with the participation of nickel complexes that result in the formation of carbon-phosphorus (C‒P) bonds. The catalytic and non-catalytic reactions with the participation of nickel complexes as the catalysts and the reagents are described. The various classes of starting compounds and the products formed are discussed individually. The several putative mechanisms of the nickel catalysed reactions are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this phosphorus chemistry.
Keywords: catalysis; electrochemistry; nickel complexes; organic and inorganic phosphanes; organophosphorus compounds; phosphorylation.