Supramolecular Association between γ-Cyclodextrin and Preyssler-Type Polyoxotungstate

Abstract

The development of hybrid materials based on polyoxometalates constitutes a strategy for the design of multifunctional materials. The slow evaporation of an aqueous solution of [NaP₅W₃₀O₁₁₀]^14- in the presence of γ-Cyclodextrin (γ-CD) led to the crystallization of a K₆Na₈{[NaP₅W₃₀O₁₁₀]•(C₄₈H₈₀O₄₀)}•23H₂O (NaP₅W₃₀•1CD) supramolecular compound, which was characterized by single-crystal X-ray diffraction, IR-spectroscopy, thermogravimetric and elemental analyses. Structural analysis revealed the formation of 1:1 {[NaP₅W₃₀O₁₁₀]•[γ-CD]}^14- adduct in the solid state. Studies in solution by cyclic voltammetry, electrochemical impedance spectroscopy, ¹H NMR spectroscopy, and ³¹P DOSY, have demonstrated weak interactions between the inorganic anion and the macrocyclic organic molecule.

Keywords: NMR spectroscopy; XRD structure; cyclic voltammetry; electrochemical impedance spectroscopy; polyoxometalate; supramolecular adduct.