Design and Preparation Technology of Single/Dual-Cross-Linking Copolymers Based on Swida wilsoniana Oil

Ruitong Liu; Jing Yi; Shouhai Li; Jianling Xia; Mei Li; Haiyang Ding; Lina Xu; Xiaohua Yang; Na Yao

doi:10.1021/acsomega.1c02199

Design and Preparation Technology of Single/Dual-Cross-Linking Copolymers Based on Swida wilsoniana Oil

ACS Omega. 2021 Aug 19;6(34):21915-21924. doi: 10.1021/acsomega.1c02199. eCollection 2021 Aug 31.

Authors

Ruitong Liu^{1

2

3

4

5}, Jing Yi^{1

2

3

4

5}, Shouhai Li^{1

2

3

4

5

6}, Jianling Xia^{1

2

3

4

5

6}, Mei Li^{1

2

3

4

5

6}, Haiyang Ding^{1

2

3

4

5

6}, Lina Xu^{1

2

3

4

5

6}, Xiaohua Yang^{1

2

3

4

5

6}, Na Yao^{1

2

3

4

5

6}

Affiliations

¹ Institute of Chemical Industry of Forestry Products, CFA, Nanjing 210042, Jiangsu Province, China.
² Key Laboratory of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China.
³ Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210042, Jiangsu Province, China.
⁴ Key and Open Laboratory of Forest Chemical Engineering, SFA, Nanjing 210042, Jiangsu Province, China.
⁵ National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, Jiangsu Province, China.
⁶ Institute of Forest New Technology, CFA, Beijing 100091, China.

Abstract

To fully utilize the forestry bioresources, a novel dual-cross-linkable resin monomer of MAHSWAGMA was prepared from Swida wilsoniana oil (SWO). FT-IR and ¹H-NMR analysis demonstrated the successful synthesis of the target product. Five different cross-linking copolymers, including a polymerized vinyl ester/single-cross-linking (PVESC) polymer, a polymerized epoxy/single-cross-linking (PESC) copolymer, a thermal-photo-initiated/dual-cross-linking (TPIDC) copolymer, a photo-thermal-initiated/dual-cross-linking copolymer (PTIDC), and a thermal-initiated/dual-cross-linking copolymer (TIDC), were obtained with different preparation technologies by different initiated cross-linking processes. Thermal and mechanical properties of the five copolymers were all tested, and the effects of different preparation technologies on the properties of prepared copolymers were investigated. The prepared three dual-cross-linking copolymers had higher hardness, relative cross-linking density, glass transition temperature, and more excellent mechanical property than the other two single-cross-linking copolymers. The PTIDC copolymerized system obtained with photo first and thermal latter initiated dual-cross-linking preparation technology had the most excellent comprehensive properties. This study can provide an ideal idea for the design and preparation of dual-cross-linking copolymers based on forestry vegetable oil.