A New High-Temperature Durable Absorber Material Solution through a Spinel-Type High Solar Absorptivity Coating on Ti2AlC MAX Phase Material

ACS Appl Mater Interfaces. 2021 Sep 22;13(37):45008-45017. doi: 10.1021/acsami.1c10585. Epub 2021 Sep 8.

Abstract

Enhancing the operating temperature of concentrating solar power systems is a promising way to obtain higher system efficiency and thus enhance their competitiveness. One major barrier is the unavailability of suitable solar absorber materials for operation at higher temperatures. In this work, we report on a new high-temperature absorber material by combining Ti2AlC MAX phase material and iron-cobalt-chromite spinel coating/paint. This durable material solution exhibits excellent performance, passing the thermal stability test in an open-air environment at a temperature of 1250 °C for 400 h and at 1300 °C for 200 h. The results show that the black spinel coating can offer a stable high solar absorptivity in the range of 0.877-0.894 throughout the 600 h test under high temperatures. These solar absorptivity values are even 1.6-3.3% higher than that for the sintered SiC ceramic that is a widely used solar absorber material. Divergence of solar absorptivity during these relatively long testing periods is less than 1.1%, indicating remarkable stability of the absorber material. Furthermore, considering the simple application process of the coating/painting utilizing a brush followed by curing at relatively low temperatures (room temperature, 95 and 260 °C in sequence), this absorber material shows the potential for large-scale, high-temperature solar thermal applications.

Keywords: MAX phase; concentrating solar power; iron–cobalt–chromite spinel coating; solar receiver; spectral hemispherical absorptivity; thermal stability.