Efficiency Boost in Dye-Sensitized Solar Cells by Post- Annealing UV-Ozone Treatment of TiO2 Mesoporous Layer

Dariusz Augustowski; Maciej Gala; Paweł Kwaśnicki; Jakub Rysz

doi:10.3390/ma14164698

Efficiency Boost in Dye-Sensitized Solar Cells by Post- Annealing UV-Ozone Treatment of TiO₂ Mesoporous Layer

Materials (Basel). 2021 Aug 20;14(16):4698. doi: 10.3390/ma14164698.

Authors

Dariusz Augustowski^{1

2}, Maciej Gala¹, Paweł Kwaśnicki^{2

3}, Jakub Rysz¹

Affiliations

¹ Department of Advanced Materials Engineering, Faculty of Physics, Astronomy and Applied Computer Science, Jagiellonian University, Łojasiewicza 11, 30-348 Cracow, Poland.
² Research & Development Centre for Photovoltaics, ML System S.A. Zaczernie 190G, 36-062 Zaczernie, Poland.
³ Department of Physical Chemistry and Physicochemical Basis of Environmental Engineering, Institute of Environmental Engineering in Stalowa Wola, John Paul II Catholic University of Lublin, Kwiatkowskiego 3A, 37-450 Stalowa Wola, Poland.

Abstract

The organic residues on titanium(IV) oxide may be a significant factor that decreases the efficiency of dye-sensitized solar cells (DSSC). Here, we suggest the UV-ozone cleaning process to remove impurities from the surface of TiO₂ nanoparticles before dye-sensitizing. Data obtained from scanning electron microscopy, Kelvin probe, Fourier-transform infrared spectroscopy, and Raman spectroscopy showed that the amounts of organic contamination were successfully reduced. Additionally, the UV-VIS spectrophotometry, spectrofluorometry, and secondary ion mass spectrometry proved that after ozonization, the dyeing process was relevantly enhanced. Due to the removal of organics, the power conversion efficiency (PCE) of the prepared DSSC devices was boosted from 4.59% to 5.89%, which was mostly caused by the increment of short circuit current (J_sc) and slight improvement of the open circuit voltage (V_oc).

Keywords: UV-ozone treatment; dye-sensitized solar cells; photovoltaics; solar cells.

Abstract

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