Microstructure and Mechanical Properties of Wire Arc Additively Manufactured MoNbTaWTi High Entropy Alloys

Jian Liu; Jing Li; Xian Du; Yonggang Tong; Rui Wang; Dongyu He; Zhihai Cai; Haidou Wang

doi:10.3390/ma14164512

Microstructure and Mechanical Properties of Wire Arc Additively Manufactured MoNbTaWTi High Entropy Alloys

Materials (Basel). 2021 Aug 11;14(16):4512. doi: 10.3390/ma14164512.

Authors

Jian Liu¹, Jing Li¹, Xian Du¹, Yonggang Tong², Rui Wang¹, Dongyu He³, Zhihai Cai¹, Haidou Wang¹

Affiliations

¹ National Engineering Research Center for Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China.
² College of Automotive and Mechanical Engineering, Changsha University of Science & Technology, Changsha 410000, China.
³ National Key Laboratory for Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China.

Abstract

High-temperature resistant high-entropy alloys (HEAs) have attracted extensive attention due to their excellent thermodynamic stability and mechanical properties, especially at high temperatures. However, a highly effective method for large-size HEAs is still desirable but challengeable. This research reported a facile yet effective strategy for MoNbTaWTi HEAs via in-situ wire arc additive manufacturing (WAAM). The wire was MoNbTaWTi cable-type welding wire (CTWW) consisting of one center wire and seven twisted peripheral wires. Then, additive manufacturing of MoNbTaWTi high entropy alloys (HEAs) was accomplished, and various analytical techniques studied the microstructures and mechanical properties of the overlaying formed layers. X-ray diffraction showed the overlaying formed layers to contain a single disordered BCC solid solution phase with high-temperature structural stability. In addition, the single-phase BCC structure was maintained from 0 to 1400 °C. The bottom of the overlaying formed layers was made of columnar cellular structure, and the upper part resembled "cauliflower-like" fine dendrite and equiaxed crystal structure. The hardness of the overlaying formed layers averaged 533 HV_0.2 at room temperature. At 1000 °C, the hardness was around 110 HV₁, close to the value of Inconel 718 alloy (125 HV₁). The compressive strength of the overlaying formed alloy layers displayed no sensitivity towards change in temperature from 500 to 1000 °C. As the temperature rose from 500 to 1000 °C, the compressive strength changed from 629 to 602 MPa, equivalent to only a 27 MPa decrease. The latter was much higher than the strength of Inconel 718 alloy at the same temperature (200 MPa).

Keywords: HEAs; MoNbTaWTi; microstructure and properties; wire arc additive manufacturing.