Series of partially fluorinated sulfonated poly(arylene ether)s were synthesized through nucleophilic substitution polycondensation from three types of diols and superhydrophobic tetra-trifluoromethyl-substituted difluoro monomers with postsulfonation to obtain densely sulfonated ionomers. The membranes had similar ion exchange capacities of 2.92 ± 0.20 mmol g-1 and favorable mechanical properties (Young's moduli of 1.60-1.83 GPa). The membranes exhibited considerable dimensional stability (43.1-122.3% change in area and 42.1-61.5% change in thickness at 80 °C) and oxidative stability (~55.5%). The proton conductivity of the membranes, higher (174.3-301.8 mS cm-1) than that of Nafion 211 (123.8 mS cm-1), was the percent conducting volume corresponding to the water uptake. The membranes were observed to comprise isolated to tailed ionic clusters of size 15-45 nm and 3-8 nm, respectively, in transmission electron microscopy images. A fuel cell containing one such material exhibited high single-cell performance-a maximum power density of 1.32 W cm2 and current density of >1600 mA cm-2 at 0.6 V. The results indicate that the material is a candidate for proton exchange membranes in fuel cell applications.
Keywords: fuel cell; ionomers; poly(arylene ether)s; proton exchange membranes.