Compositional and morphological properties of platinum-iridium electrodeposited on carbon fiber microelectrodes

J Neural Eng. 2021 Sep 13;18(5):10.1088/1741-2552/ac20bb. doi: 10.1088/1741-2552/ac20bb.

Abstract

Objective. Neural interfaces based on carbon fiber (CF) electrodes have demonstrated key positive attributes such as minimal foreign body response and mechanical strength to self-insert in brain tissue. However, carbon does not form a low impedance electrode interface with neural tissue. Electrodeposited platinum iridium (PtIr) has been used to improve electrode interface properties for metallic bioelectrodes.Approach. In this study, a PtIr electrodeposition process has been performed on CF microelectrode arrays to improve the interfacial properties of these arrays. We study the film morphology and composition as well as electrode durability and impedance.Results. A PtIr coating with a composition of 70% Pt, 30% Ir and a thickness of ∼400 nm was observed. Pt and Ir were evenly distributed within the film. Impedance was decreased by 89% @ 1 kHz. Accelerated soak testing in a heated (T= 50C) saline solution showed impedance increase (@ 1 kHz) of ∼12% after 36 days (89 equivalent) of soaking.

Keywords: carbon fiber microelectrodes; electrode coating; electron microscopy; neural interfaces; platinum-iridium electrochemical deposition.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon Fiber
  • Electric Impedance
  • Electroplating
  • Iridium*
  • Microelectrodes
  • Platinum*

Substances

  • Carbon Fiber
  • Iridium
  • Platinum