Multiple ions detection by field-effect transistor sensors based on ZnO@GO and ZnO@rGO nanomaterials: Application to trace detection of Cr (III) and Cu (II)

Abstract

This work narrates the preparation of efficient nanomaterials framework of zinc oxide (ZnO) nanoglobules (NGs) with graphene oxide (GO) and reduced graphene oxide (rGO) for the fabrication of rapid multiple ion field-effect transistor (MI-FET) sensors. Prepared ZnO-NGs@GO and ZnO-NGs@rGO nanocomposites were broadly analyzed by different analytical techniques to study their morphological, structural, compositional, and electrochemical properties. As electrode materials, ZnO-NGs@GO and ZnO-NGs@rGO were used to fabricate MI-FETs sensor for the detection of multiple ions such as Ni (II), Co (II), Cu (II), Cr (III), Fe (II), and Bi (II) ions. ZnO-NGs@GO and ZnO-NGs@rGO modified MI-FETs sensor exhibited excellent responses towards Cr (III) and Cu (II) ions, which presented the remarkable sensitivities of ~49.28 mA μM^-1. cm^-2 (Cr (III) ions) and ~185.32 mA μM^-1. cm^-2 (Cu (II) ions), respectively. The fabricated MI-FETs sensor displayed good dynamic linear detection of ions with low limit of detection (LOD) values of ~7.05 μM and ~14.9 μM for ZnO-NGs@GO and ZnO-NGs@rGO electrodes, respectively. Efficient charge transfer over electrode considerably enhanced the trace detection of Cr (III) and Cu (II) ions. The fabricated MI-FETs sensor platform exhibited extraordinary reproducibility and excellent stability of sensing performance and thus, confirmed delightful potential to sprout a useful tool for water maintaining system.

Keywords: Environmental remediation electrochemical; FETs; Graphene; Heavy metal ions; Zinc oxide.