Carbendazim (CBZ) is a fungicide employed in grape crop disease controls, and its maximum residue limit in food is regulated by specialized agencies. This study aimed to determine the CBZ content in the grape juices in a semi-quantitative classification model based on portable Ultraviolet-Visible spectroscopy and partial least squares with discriminant analysis. The sensitivity and specificity of the obtained model ranged from 83 to 100%, with the external validation set. These results are therefore promising for industrial application, and the model presents robustness for the evaluation of grape juices produced from a different grape variety. The VIP scores allowed identifying important variables involved in class modeling. This study suggests a methodology that is fast and demands minimal sample preparation (only dilution), besides being less expensive compared to the traditional methods, free of reagent/solvent, contributing to quality control in the juice industry.
Keywords: Carbendazim; Chemometrics; Classification; Grape; Robustness; Spectroscopy.
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