The electrochemical oxygen evolution reaction (OER) is an important half-cell reaction in many renewable energy conversion and storage technologies, including electrolyzers, nitrogen fixation, CO2 reduction, metal-air batteries, and regenerative fuel cells. Among them, proton exchange membrane (PEM)-based devices exhibit a series of advantages, such as excellent proton conductivity, high durability, and good mechanical strength, and have attracted global interest as a green energy device for transport and stationary sectors. Nevertheless, with a view to rapid commercialization, it is urgent to develop highly active and acid-stable OER catalysts for PEM-based devices. In this Review, based on the recent advances in theoretical calculation and in situ/operando characterization, the OER mechanism in acidic conditions is first discussed in detail. Subsequently, recent advances in the development of several types of acid-stable OER catalysts, including noble metals, non-noble metals, and even metal-free OER materials, are systematically summarized. Finally, the current key issues and future challenges for materials used as acidic OER catalysis are identified and potential future directions are proposed.
Keywords: acidity; electrocatalysis; energy conversion; operando characterization; oxygen evolution reaction.
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