Chemical characteristics of groundwater and source identification in a coastal city

PLoS One. 2021 Aug 19;16(8):e0256360. doi: 10.1371/journal.pone.0256360. eCollection 2021.

Abstract

A coastal city is studied in this paper. Based on 42 groundwater sampling points, a Piper diagram, the Shukarev classification, the Pearson correlation analysis, Gibbs plots and the ion proportional coefficient method are used to analyze the chemical characteristics and material source. The results show that the groundwater quality in the study area varies greatly from north to south. In the northern inland area (AREA I), the main anions and cations are [Formula: see text] and Ca2+, and the hydrochemical characteristics are mainly HCO3 - Ca, HCO3 ⋅ SO4 - Ca and HCO3 - Mg. The ion concentration distribution is uniform, and the groundwater quality is good. By using Gibbs plots and the ion proportional coefficient method, the main source of ions is the dissolution of potassium feldspar, albite and carbonate rock. In contrast, in the southern coastal area (AREA II), the main anions and cations are Cl- and Na+, and the hydrochemical characteristics are mainly Cl - Na. The ion concentration distribution presents a strong spatial difference. The closer the groundwater sampling point is to seawater, the worse the overall groundwater quality. Evaporite dissolution, seawater intrusion, cation exchange effects and human activities are the main factors affecting the groundwater quality in this area. In conclusion, the groundwater quality in northern inland area (AREA I) is better, mainly controlled by the dissolution of rocks. The groundwater quality in southern coastal area (AREA II) changes greatly, mainly controlled by seawater.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cities
  • Environmental Monitoring
  • Groundwater*
  • Water Pollutants, Chemical / analysis
  • Water Quality

Substances

  • Water Pollutants, Chemical

Grants and funding

The Qingdao Real Estate Architectural Design Institute Co., Ltd. provided support in the form of salary for author YX, but did not have any additional role in the study design, data collection and analysis, decision to publish, or preparation of the manuscript. The specific roles of this author are articulated in the ‘author contributions’ section. The authors received no other specific funding for this work.