To date, aluminyl anions have been exclusively isolated as their potassium salts. We report herein the synthesis of the lithium and sodium aluminyls, M2 [Al(NONDipp )]2 (M=Li, Na. NONDipp =[O(SiMe2 NDipp)2 ]2- ; Dipp=2,6-iPr2 C6 H3 ). Both compounds crystallize from non-coordinating solvent as "slipped" contacted dimeric pairs with strong M⋅⋅⋅π(aryl) interactions. Isolation from Et2 O solution affords the monomeric ion pairs (NONDipp )Al-M(Et2 O)2 , which contain discrete Al-Li and Al-Na bonds. The ability of the full series of Li, Na and K aluminyls to activate dihydrogen is reported.
Keywords: aluminyl anion; dihydrogen activation; lithium aluminyl; sodium aluminyl.
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