A comparative study on the thermal runaway inhibition of 18650 lithium-ion batteries by different fire extinguishing agents

Junchao Zhao; Feng Xue; Yangyang Fu; Yuan Cheng; Hui Yang; Song Lu

doi:10.1016/j.isci.2021.102854

A comparative study on the thermal runaway inhibition of 18650 lithium-ion batteries by different fire extinguishing agents

iScience. 2021 Jul 10;24(8):102854. doi: 10.1016/j.isci.2021.102854. eCollection 2021 Aug 20.

Authors

Junchao Zhao¹, Feng Xue¹, Yangyang Fu¹, Yuan Cheng¹, Hui Yang¹, Song Lu¹

Affiliation

¹ State Key Laboratory of Fire Science, University of Science of Technology of China, Hefei, Anhui, 230026, P.R.China.

Abstract

Safety issue of lithium-ion batteries (LIBs) is always a concern. We have studied the inhabitation on thermal runaway (TR) and propagation of 18,650 LIBs in an enclosed space systematically. LIBs at 70% state of charge are chosen for testing. Four fire extinguishing agents are applied on LIB arrays for 20 s, and the inhibiting effects are different. The cooling efficiency varies with the surface temperatures of LIBs. Water spray has the highest cooling efficiency and inhibits the TR propagation among LIB arrays successfully. Three LIBs undergo TR for the releasing of ABC ultrafine dry powder. BC ultrafine dry powder and Novec 1230 are failed to inhibit the TR propagation. Nevertheless, Novec 1230 shows the best on inhibiting fire occurring and the generation of toxic gas. Generally, this study provides valuable information for the choice of fire extinguishing agents.

Keywords: Chemistry; Electrochemical Energy Storage; Electrochemistry.