Oxygen reduction reaction (ORR) is an efficiency-determining process at the cathode in several energy storage and conversion devices, typically such as metal-air batteries and fuel cells. To date, a considerable amount of ORR electrocatalysts have been purposely exploited to address the key issues of high overpotentials and sluggish electrochemical kinetics. Electrospinning is a popular additive manufacturing technology, enabling the production of one-dimensional (1D) electrocatalysts with outstanding chemical stability and structural diversity. However, compared with the well-studied composite/structural design as well as performance advancement, insights into structure-activity relationship are yet to be settled. To clarify this key issue, herein, a dedicated review on the structure-activity relationship between the 1D architectures of electrospun electrocatalysts and their catalytic ORR property is presented. First, the development and principles of electrospinning technique, the composition regulation- and structure design-oriented fundamentals are summarized by imputing the perspectives of mechanistic understanding. Then, the typical examples of nanofiber-shaped and nanofiber-supported electrocatalysts with different compositions and structures for ORR are implemented to establish different structure-activity relationship by comparative studies. Finally, we also identify some ongoing challenges and present future perspectives to direct the precise manipulation of structure-activity relationship for further activation and optimization of electrospun 1D electrocatalysts.
Keywords: ORR; electrocatalysts; electrospinning; nanofibers; structure−activity relationship.