Groundwater Pollution Source Identification and Apportionment Using PMF and PCA-APCS-MLR Receptor Models in Tongchuan City, China

Abstract

Potential sources of groundwater pollution in Tongchuan City, China, were qualitatively identified based on 14 key water quality indicators of 59 groundwater samples, and the contribution of each source to groundwater quality was quantitatively evaluated. Groundwater pollution sources were analyzed using PMF and PCA-APCS-MLR models, and their applicability in groundwater pollution assessment in Tongchuan City was tested. Results indicate that both models identified four sources of groundwater contamination. Natural evolution was the main cause of groundwater pollution in the study area, followed by the coal industry, agriculture, and urbanization. Although the spatial distribution of pollution sources in the two models differed, the urbanized area to the east of the study area was more severely affected by sewage discharge, the west was more obviously affected by the coal industry, and the north was mainly polluted by agriculture. Both of the fitting results of the two models are good, but R² values obtained by the PMF model (0.4440-0.9991) were generally higher than those obtained by the PCA-APCS-MLR model (0.5180-0.9530), indicating that PMF model results were more accurate than the PCA-APCS-MLR model.