The co-transport of Cd(Ⅱ) with nanoscale As2S3 in soil-packed column: Effects of ionic strength

Abstract

To observe the co-transport of Cd(Ⅱ) with nanoscale As₂S₃ (nAs₂S₃) in a soil-packed column under different ionic strength (IS). A soil-packed column experiment with Cd(Ⅱ) and nAs₂S₃ was conducted. The results show that the transport of Cd(Ⅱ) was facilitated remarkably in the presence of nAs₂S₃, and nano-associated-Cd(Ⅱ) was the major migration type. However, the co-transport of Cd(Ⅱ) and nAs₂S₃ was affected by IS. The Cd(Ⅱ) concentration in the effluent to initial Cd(Ⅱ) concentration decreased from 38.75% to 29.95% and 22.28% as IS increased from 1 mM to 10 mM and 50 mM. When IS was 1 mm, 10 mm and 50 mm, the retention of nAs₂S₃ increased from 74.29% to 78.95% and 85.9% respectively. The agglomeration and sedimentation of nAs₂S₃ were the main reason for the rise of retention. Due to the increase of retention and reduction in adsorption capacity of nAs₂S₃ to Cd(Ⅱ), the ratio of migration in the form of nano-associated-Cd(Ⅱ) reduced from 53% (IS 1 mM) to 27.4% (IS 10 mM) and 18.2% (IS 50 mM). During the transport, the IS promoted desorption of Cd(Ⅱ) from nAs₂S₃ so that more soluble Cd was monitored in the effluent as IS increased. In general, these findings can provide references for controlling the risk caused by the co-transport of nAs₂S₃ and Cd(Ⅱ) in saline-alkali soil.

Keywords: As(2)S(3) nanoparticles; Cadmium; Co-transport; Soil.