We propose a single-atom, cavity quantum electrodynamics system, compatible with recently demonstrated, fiber-integrated micro- and nanocavity setups, for the on-demand production of optical number-state, 0N-state, and binomial-code-state pulses. The scheme makes use of Raman transitions within an entire atomic ground-state hyperfine level and operates with laser and cavity fields detuned from the atomic transition by much more than the excited-state hyperfine splitting. This enables reduction of the dynamics to that of a simple, cavity-damped Tavis-Cummings model with the collective spin determined by the total angular momentum of the ground hyperfine level.