Nanoflakes-like nickel cobaltite as active electrode material for 4-nitrophenol reduction and supercapacitor applications

Abstract

Catalytic reduction of nitroaromatic compounds present in wastewater by nanostructured materials is a promising process for wastewater treatment. A multifunctional electrode based on ternary spinal nickel cobalt oxide is used in the catalytic reduction of a nitroaromatic compound and supercapacitor application. In this study, we designed nanoflakes- like nickel cobaltite (NiCo₂O₄) using a simple, chemical, cost-effective hydrothermal method. Nanoflakes- like NiCo₂O₄ samples are tested as catalysts toward rapid reduction of 4-nitrophenol and as electrode materials for supercapacitors. The conversion of 4-nitrophenol into 4-aminophenol is achieved using a reducing agents like sodium borohydride and NiCo₂O₄ catalyst. Effect of catalyst loading, 4-nitrophenol and sodium borohydride concentrations on the catalytic performance of 4-nitrophenol is studied. As sodium borohydride concentration increases the catalytic efficiency of 4-nitrophenol increased due to more BH₄^- ions available which provides more electrons for catalytic reduction of 4-nitrophenol. Catalytic reduction of 4-nitrophenol using sodium borohydride as a reducing agent was based on the Langmuir-Hinshelwood mechanism. This mechanism follows the apparent pseudo first order reaction kinetics. Additionally, NiCo₂O₄ electrode is used for energy storage application. The nanoflakes-like NiCo₂O₄ electrode deposited at 120 °C shows a higher specific capacitance than samples synthesized at 100 and 140 °C. The maximum specific capacitance observed for NiCo₂O₄ electrode is 1505 Fg^-1 at a scan rate of 5 mV s^-1 with high stability of 95% for 5000 CV cycles.

Keywords: 4-Nitrophenol; Catalytic reduction; Electrochemical properties; Hydrothermal method; NiCo(2)O(4) nanoflakes; Supercapacitors.