Highly efficient and recyclable polyolefin-based magnetic sorbent for oils and organic solvents spill cleanup

Abstract

The oil dispersants have been applied in a broad oil pollution area, but the dispersed oil caused environmental problems during sedimentation. Unlike oil dispersants, flake type polyolefin-based oil absorbent (PA) is not emulsified and shows excellent swelling characteristic for oil removal. However, the sprayed PA flakes cannot be fully collected due to its tiny architectures, the uncollected flakes can cause unintentional secondary pollution. In this study, we develop a kind of flake type polyolefin-based magnetic absorbent (PMA) hybridized with magnetic nanoparticle, to facilitate the collection process. The magnetic nanoparticle is uniformly dispersed in PMA due to the hydrophobic functionalization of iron oxide nanoparticle. This enables the convenient collection of isolated sorbent flakes even when they were placed in the marine system and show a desirable oil recovery performance up to about 37 times for organic solvent. Moreover, oil-soaked PMA flakes can be fully converted into refined oil via a pyrolysis process. After pyrolysis, the thermally undecomposed compounds, which comprise of carbon residue and magnetic nanoparticle, can be also separated by a magnet. The as-prepared flake type PMA possesses good oil recovery performance, fast magnetic response, and efficient oil recycling, thus representing an environmentally promising method for oil spill cleanup.

Keywords: Magnetic nanoparticle; Oil recycling; Oil spill; Polyolefin; Sorbent.