Hydride species on oxide catalysts

Zhaorui Li; Weixin Huang

doi:10.1088/1361-648X/ac17ad

Hydride species on oxide catalysts

J Phys Condens Matter. 2021 Aug 12;33(43). doi: 10.1088/1361-648X/ac17ad.

Authors

Zhaorui Li¹, Weixin Huang^{1

2}

Affiliations

¹ Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, People's Republic of China.
² Dalian National Laboratory for Clean Energy, Dalian 116023, People's Republic of China.

PMID: 34311453
DOI: 10.1088/1361-648X/ac17ad

Abstract

Hydride species on oxide catalysts are widely involved in oxide-catalyzed reactions, and relevant fundamental understanding is important to establish reaction mechanisms and structure-performance relations of oxide catalysts. In this topical review, recent progresses on the formation and reactivity of hydride species on the surface or in the bulk of oxides are briefly summarized. Firstly, characterization techniques for hydride species are introduced. Secondly, formation of hydride species on the surface or in the bulk of various oxides and their reactivity in oxide-catalyzed hydrogenation and dehydrogenation reactions are reviewed. Finally, short summary and outlook are given.

Keywords: H2; dehydrogenation; heterogeneous catalysis; hydrocarbon; hydrogenation; surface chemistry.

Publication types

Review