Development and characterization of aldehyde-sensitive cellulose/chitosan/beeswax colorimetric papers for monitoring kiwifruit maturity

Int J Biol Macromol. 2021 Sep 30:187:566-574. doi: 10.1016/j.ijbiomac.2021.07.132. Epub 2021 Jul 23.

Abstract

In this study, we developed an in-package colorimetric paper to monitor the ripeness of kiwifruit by detecting the release of aldehydes. Strongly hydrophobic composite films were prepared using chitosan as the matrix and beeswax as an additive. A piece of cellulose paper containing methyl red and bromocresol violet as color indicators was heat-sealed between two hydrophobic films to protect the indicators from the effects of fruit respiration and transpiration. The nucleophilic addition reaction between aldehydes and OH- (Cannizzaro reaction) changes the pH in the paper and triggers a color change in the indicators. As the kiwifruit ripens, the colorimetric paper changes from bluish-purple to dark red and then gradually to red. A mobile phone application was further used to measure the RGB values and link them to kiwifruit ripeness. This intelligent paper can be used for the accurate and convenient monitoring of produce in real time.

Keywords: Aldehyde; Colorimetric paper; Kiwifruit.

MeSH terms

  • Actinidia / metabolism*
  • Aldehydes / metabolism*
  • Azo Compounds / chemistry
  • Cellulose / chemistry*
  • Color
  • Colorimetry
  • Coloring Agents / chemistry
  • Food Packaging*
  • Food Quality
  • Food Storage
  • Fruit / metabolism*
  • Paper*
  • Smart Materials*
  • Time Factors
  • Waxes / chemistry*

Substances

  • Aldehydes
  • Azo Compounds
  • Coloring Agents
  • Smart Materials
  • Waxes
  • beeswax
  • methyl red
  • Cellulose