Highlighting Thermo-Elastic Effects in Confined Fluids

Polymers (Basel). 2021 Jul 20;13(14):2378. doi: 10.3390/polym13142378.

Abstract

The recent identification of a finite shear elasticity in mesoscopic fluids has motivated the search of other solid-like properties of liquids. We present an innovative thermal approach of liquids. We identify a dynamic thermo-elastic mesoscopic behavior by building the thermal image produced by different liquids upon applying a low frequency mechanical shear field. We selected three fluids: a low molecular weight polybutylacrylate (PBuA), polypropyleneglycol (PPG), and glycerol. We demonstrate that a part of the energy of the shear strain is converted in cold and hot shear bands varying synchronously with the applied shear field. This thermodynamic change suggests a coupling to shear elastic modes in agreement with the low frequency shear elasticity theoretically foreseen and experimentally demonstrated.

Keywords: adiabatic transformation; glass former; liquid state; polymer melt; shear elasticity; shear strain; thermo-elasticity.