Gold Leaching from an Oxide Ore Using Thiocyanate as a Lixiviant: Process Optimization and Kinetics

Atefeh Azizitorghabeh; Harshit Mahandra; Juliana Ramsay; Ahmad Ghahreman

doi:10.1021/acsomega.1c00525

Gold Leaching from an Oxide Ore Using Thiocyanate as a Lixiviant: Process Optimization and Kinetics

ACS Omega. 2021 Jun 29;6(27):17183-17193. doi: 10.1021/acsomega.1c00525. eCollection 2021 Jul 13.

Authors

Atefeh Azizitorghabeh¹, Harshit Mahandra¹, Juliana Ramsay², Ahmad Ghahreman¹

Affiliations

¹ Hydrometallurgy and Environment Laboratory, Robert M. Buchan Department of Mining, Queen's University, 25 Union Street, Kingston, Ontario K7L 3N6, Canada.
² Department of Chemical Engineering, Queen's University, 19 Division Street, Kingston, Ontario K7L 3N6, Canada.

Abstract

Thiocyanate (SCN^-) is a promising alternative to cyanide as a lixiviant for gold extraction and is 1000 times less toxic than cyanide. In this study, the following leaching parameters were tested to optimize the gold recovery for the first time from an oxide ore using the response surface methodology: initial thiocyanate concentration (10-500 mM), initial Fe³⁺ concentration (10-500 mM), and pulp density (10-50% w/v). The maximum gold recovery (96%) was achieved with 500 mM thiocyanate, 100 mM Fe³⁺, and 50% pulp density at 25 °C and pH = 2 for 24 h. A kinetic study on the optimum leaching condition showed that it followed the shrinking core model, in which the rate-controlling mechanism was the diffusion process. These results are discussed in the context of the published literature.