Comparative investigation of acetaminophen degradation in aqueous solution by UV/Chlorine and UV/H2O2 processes: Kinetics and toxicity assessment, process feasibility and products identification

Abstract

The degradation of acetaminophen (ACM) was comparatively studied by UV/chlorine and UV/H₂O₂ systems. An apparent reduction in the removal rate was observed above the optimum pH levels of 7.0 and 3.0 in UV/chlorine and UV/H₂O₂ processes, respectively. The relative contribution of each oxidizing agent in ACM removal using the two advanced oxidation processes (AOPs) was evaluated. Even though hydroxyl radicals, with the contribution percentage of 90.1%, were determined as the primary oxidizing species in ACM removal using the UV/H₂O₂ process, reactive chlorine species (RCS), with 43.8% of contribution percentage, were also found to play a pivotal role in ACM removal using the UV/chlorine process. For instance, dichlorine radical (Cl₂^•-) showed an acceptable contribution percentage of 32.2% in the degradation of ACM by the UV/chlorine process. The rate of ACM degradation significantly rose to 99.9% and 75.6%, as higher amounts of oxidants were used in the UV/chlorine and UV/H₂O₂ processes, respectively, within 25 min. The introduction of HCO₃^- ions and humic acid remarkably decreased the rate of ACM degradation in both techniques used in this study. The presence of NO₃^- and Cl^- ions did not considerably affect the removal rate in the UV/chlorine process. The acute toxicity analysis revealed that a more pronounced reduction in the ACM solution toxicity could be achieved by the UV/H₂O₂ process compared to the UV/chlorine process, which should be ascribed to the formation of chlorinated products in the UV/chlorine treatment. Eventually, plausible oxidation pathways were proposed for each process.

Keywords: Acetaminophen; Advanced oxidation processes (AOPs); Chlorine; Degradation pathway; Hydrogen peroxide; Toxicity assessment.