The exploiting of abundant natural polymers as potential absorbents for heavy metal ions is attracting. Cellulose is the most abundant natural polymer and exhibits amazing properties such as high chemical stability, hydrophilicity and biodegradability. However, some properties of pure cellulose-based materials including adsorbability are usually not enough, so it is important to improve their properties to broaden their applications. In the present work, hydroxyapitite (HAP) nanoparticles were prepared and introduced to improve the cellulose hydrogel (CG) properties. The structure and properties of the resultant cellulose/HAP nanocomposite hydrogels (CHG) were characterized and studied systematically. The results indicated that HAP nanoparticles was fixed and distributed evenly in CG. The maximum decomposition temperature increased gradually from 334.6 °C for CG to 346.7 °C for CHG, and the compressive strength increased gradually from 100 kPa for CG to 570 kPa for CHG with the increase of HAP content, respectively. Moreover, the adsorption capacity (qe) value of CHG towards Cu2+ could reach more than 300% higher than that of CG. As a potential absorbent, CHG exhibited relatively good recyclability of more than 78% after 10 cycles. Therefore, the introduction of HAP improved the properties of CG greatly, showing wide potential applications.
Keywords: Cellulose hydrogels; Hydroxyapatite nanoparticles; Properties improvement.
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