Enhanced oil recovery using hyperbranched polyglycerol polymer-coated silica nanoparticles

Abstract

Functionalized Fe₃O₄-SiO₂ magnetic nanoparticles (Fe-Si-MNPs) coated with hyperbranched polyglycerol polymer were prepared and tested for oil recovery from oil in water (O/W) emulsions. The structure, chemistry, and surface modifications of the newly developed demulsifier (PSiMNPs) were analyzed, and the percentage demulsification efficiency (%η_dem) was tested at differing concentrations of surfactant (C_sur), oil (C_oil), and demulsifier (D_PSiMNPs). The developed PSiMNPs can be separated from the solution by a magnetic field, regenerated using ethanol, and reused several times. The reported %η_dem was ≥80% for all the studied C_oil. The %η_dem improved as the C_sur and pH decreased, with maximum values of 98.8% and 98.5% achieved at C_sur = 0.05 g/L and a pH = 4, respectively. A D_PSiMNPs = 100 mg/L was sufficient to achieve %η_dem of 99.4% for C_oil = 100 mg/L and slightly decreased to ~93% for C_oil ~4000 mg/L. The PSiMNPs can be reused up to 15 times with a steady %η_dem of 89.1% for C_oil = 100 mg/L and 88.6% for C_oil = 4000 mg/L. The adsorption of oil on the PSiMNPs follows Freundlich isotherm with maximum adsorption capacity (q_max) of 192.8 g/mg and Langmuir constant (b) of 28.06 mg/L for C_oil = 900 mg/L. The q_max of the recycled PSiMNPs slightly decreased to 189.08 g/mg. The kinetic of oil recovery follows the PSO with a K₂ of 0.0169 g/mg. min. Surface modification of Fe-Si-MNPs enhanced the oil adsorption, increased the adsorption capacity, and extended the service life resulting in a better cost and process feasibility.

Keywords: Demulsification efficiency; Oil in water (O/W) emulsion; Oil removal; PSiMNPs.