Evaluation of easy-removing antioxidant films of chitosan with Melaleuca alternifolia essential oil

Int J Biol Macromol. 2021 Sep 1:186:365-376. doi: 10.1016/j.ijbiomac.2021.07.035. Epub 2021 Jul 8.

Abstract

Chitosan - tea tree essential oil (TTEO) films were obtained as a new biodegradable material. Malic acid or lactic acid solvents were evaluated to obtain easy-removing films. The microstructure by SEM and FT-IR, the thermal properties by TGA/DSC, the mechanical properties, the water vapor permeability, the antioxidant (DPPH and ABTS•+) activity and the optical properties of the formulated films were evaluated. A complete dissolution of the film in water was obtained. The elongation to break was higher in the films with malic acid (145.88-317.33%), comparing with those with lactic acid (25.54-44.08%). Chitosan film obtained in malic acid with TTEO showed the highest antioxidant activity. The colour and transparency of the samples did not suffer significant variations by TTEO addition. Films showed good UV-barrier properties, with a slightly improvement by TTEO addition. The films obtained showed a great potential for food packaging applications.

Keywords: Chitosan; Film; Tea tree essential oil.

Publication types

  • Comparative Study

MeSH terms

  • Antioxidants / chemistry
  • Antioxidants / pharmacology*
  • Benzothiazoles / chemistry
  • Biphenyl Compounds / chemistry
  • Chitosan / chemistry*
  • Color
  • Elastic Modulus
  • Food Packaging*
  • Lactic Acid / chemistry
  • Malates / chemistry
  • Picrates / chemistry
  • Solubility
  • Solvents / chemistry
  • Sulfonic Acids / chemistry
  • Surface Properties
  • Tea Tree Oil / chemistry
  • Tea Tree Oil / pharmacology*
  • Tensile Strength
  • Water / chemistry

Substances

  • Antioxidants
  • Benzothiazoles
  • Biphenyl Compounds
  • Malates
  • Picrates
  • Solvents
  • Sulfonic Acids
  • Water
  • 2,2'-azino-di-(3-ethylbenzothiazoline)-6-sulfonic acid
  • Lactic Acid
  • Tea Tree Oil
  • malic acid
  • Chitosan
  • 1,1-diphenyl-2-picrylhydrazyl